Matching Water Soluble Fertilizer to Water Quality

Purchasing water-soluble fertilizer for your crops is not simply based on what is on sale or a matter of selecting a “geranium fertilizer” for your geraniums; it is based mostly on the quality of your water source. Water can have a significant impact on the pH of the growing medium and may also provide sufficient levels of certain beneficial nutrients, keeping them off your fertilizer program. To develop a fertilizer program, have the water tested for alkalinity, nutrient levels and electrical conductivity (EC) for the content of total salts.

What is Alkalinity? 

To develop a fertilizer program, begin with testing the alkalinity of your water. Alkalinity is not a measure of pH, but a measure of the bicarbonates and carbonates present in the water and is expressed in parts per million (ppm) calcium carbonate. Essentially, alkalinity is a measure of the quantity of “limestone” dissolved in the water. Therefore, the higher the alkalinity of a water source, the more “limestone” is applied with each irrigation and the faster the pH of the growing medium rises.

This rise can be offset by using a potentially acidic fertilizer and/or injection of acid to neutralize some of the alkalinity into a desirable range. Likewise, if the alkalinity is low, then use a fertilizer with a low potential acidity or even a fertilizer with a potential basicity.

The table below provides suggestions to help in selecting a fertilizer based on water alkalinity:

These ranges are only guidelines and assume fertilizer is applied as a constant feed, at normal rates. This information does not apply to young plant production. Guidelines will vary depending on the crop, stage of development, fertilizer rate, application frequency and irrigation schedule. 
Water alkalinity
(ppm CaCO3)
Potential basicity of fertilizer
(lb CaCO3 / ton fertilizer)*
Potential acidity of fertilizer
(lb CaCO3 / ton fertilizer)
Acid injection needed
0-60 0-200 - No
60-120 - 0-200 No
120-180 - 300-400 No
180-250 - 400-600 Maybe
250+ - Adjust alkalinity with acid to range first column. Apply the suggested fertilizer. Yes

Which Nutrients Do Plants Get From Water? 

Next, look at beneficial elements coming from the water.  Most water-soluble fertilizers provide nitrogen, phosphorus, potassium and micronutrients, but many do not provide significant levels of calcium, magnesium or sulfate. These three nutrients can come from the water and are needed continuously by plants at the following levels:

Nutrient Normal range for plants
Calcium 40-120 ppm
Magnesium 25-50 ppm
Sulfate 60-200 ppm

 

If any of these three nutrients in the fertilizer solution are found at levels below these normal ranges, then they need to be provided. Below is a guideline that suggests corrective measures if one or more of these nutrients are at insufficient levels in your fertilizer program:

*Epsom salts (magnesium sulfate) cannot be mixed with a calcium-containing fertilizer in the same stock tank. **Sulfuric acid is only needed if water alkalinity is high. 
Nutrient in fertilizer program What to do if the nutrient is low in the fertilizer program
Calcium Magnesium Sulfate
Low Sufficient Sufficient Rotate high-percent calcium fertilizer (e.g. 15-0-15) with a standard potentially acidic fertilizer
Low Low Sufficient Use / Rotate Cal-mag fertilizer (e.g. 13-2-13) OR Rotate high-percent calcium fertilizer with high magnesium feed (e.g. 18-2-18 or 18-8-17)
Low Low Low Rotate high calcium fertilizer (e.g. 15-0-15) with standard potentially acidic fertilizer plus Epson salts* OR use Cal-mag fertilizer (e.g. 13-2-13) AND inject sulfuric acid **
Low Sufficient Low Rotate high calcium fertilizer (e.g. 15-0-15) with standard potentially acidic fertilizer plus Epson salts*
Sufficient Low Sufficient Use high magnesium feed (e.g. 18-2-18 or 18-8-17) OR add Epson salts* to fertilizer
Sufficient  Low Low Add Epsom salts* to fertilizer
Sufficient Sufficient Low Inject sulfuric acid** OR add Epsom salts* to fertilizer

If a Cal-mag fertilizer or high-percent calcium fertilizer is used, remember that they are potentially basic and will cause growing medium pH to rise over time. If the water alkalinity is above 60 ppm, rotate every other feed with a potentially acidic fertilizer to offset the potential rise in growing medium pH. Below are guidelines to help determine the potential acidity of a fertilizer needed when a potentially basic fertilizer must be used:

These ranges are only guidelines and assume fertilizer is applied as a constant feed, at normal rates and both fertilizers are used every other time. These suggestions do not apply to young plant production. Guidelines will vary depending on the crop, stage of development, fertilizer rate, application frequency and irrigation schedule. 
Water alkalinity
(ppm CaCO3)
Potential basicity of fertilizer
(lb CaCO3/ ton fertilizer)*
Potential acidity of rotated fertilizer
(lb CaCO3 / ton fertilizer)
0-60 100-400 100-300
60-120 100-400 300-500
120-180 100-400 400-700
180-250 100-400 600+ OR inject acid to range in the first column
250+ 100-400 Adjust alkalinity with acid to range in the first column. Apply suggested fertilizer. 

Soluble Salts in Irrigation Water 

Finally, let's look at the total amount of soluble salts that are coming from the water. Most water sources have manageable levels of total salts, but if the E.C. of the water exceeds 0.80 mmhos/cm, then soluble salts can accumulate in the growing medium and cause problems.

Frequent leaching reduces salt build up and fertilizing at the lower end of recommended rates also reduces salt inputs into the growing medium. If the EC of the water exceeds 2.0, then the water may be unusable for crop growth unless it is blended with rain water, filtered using reverse osmosis, etc.

The composition of the soluble salts is also important. If the high salts come mostly from calcium, magnesium and sulfate, then plants can tolerate higher levels of these elements as they are nutritive elements and plants will use them. However, if the soluble salts are mostly sodium and chloride, the water can be more problematic for crop growth.

For example, if the sodium levels exceed 80 ppm and chloride 100 ppm, then crop growth can be negatively impacted as plants will take these elements up as opposed to supplied fertilizer. If these rates exceed 150 and 200 ppm, respectively, then reverse osmosis or other water treatment options may be needed.